• 书名：Catalytic Hydrolysis of Carbonyl Sulfide

ISBN：978-7-5240-0391-5

• 出版社：冶金工业出版社有限公司

• 分社部门：有色地矿编辑中心

• 定价：129

• 作者：易红宏 赵顺征 唐晓龙

• 出版时间：2025-12-12

内容简介

羰基硫是广泛存在于天然气、水煤气和工业尾气中的一种有毒有害气体。研究表明：羰基硫对工业催化剂有很强的毒化作用，微量的羰基硫就会导致催化剂的中毒。另外，羰基硫在大气中会被氧化成二氧化硫，导致酸雨和光化学烟雾。催化水解法因其能耗低、操作简便、副反应少而被认为是一种具有较好应用前景的羰基硫脱除方法。本书围绕羰基硫的低温催化水解法脱除，系统介绍了活性炭基催化剂、类水滑石衍生氧化物以及分子筛用于羰基硫水解的催化活性，考察了催化剂制备条件和水解反应条件对羰基硫脱除效率的影响，深入探讨了羰基硫低温催化水解的反应动力学及反应机理。

编辑推荐

目前有关羰基硫催化水解的书籍很少，本书提供了一个全面的技术视角。介绍了活性炭基催化剂、类水滑石衍生氧化物以及改性分子筛等新型催化剂的应用，反映了当前羰基硫催化水解技术的最新进展。

目录

CATALOGUE

FOREWORD

CHAPTER 1: PROPERTIES AND HAZARDS OF CARBONYL SULFIDE

1.1 PHYSICAL PROPERTIES OF CARBONYL SULFIDE

1.2 CHEMICAL PROPERTIES OF CARBONYL SULFIDE

1.2.1 Decomposition

1.2.2 Hydrolysis

1.2.3 Oxidation

1.2.4 Reduction

1.2.5 Reaction with sulfur dioxide

1.2.6 Reactions with ammonia and amines

1.2.7 Reaction with potassium hydroxide

1.3 SOURCES AND POLLUTION HAZARDS OF CARBONYL SULFIDE

REFERENCES

CHAPTER 2: REMOVAL METHOD OF CARBONYL SULFIDE

2.1 REDUCTION METHOD

2.2 ABSORPTION METHOD

2.3 ADSORPTION METHOD

2.4 PHOTOLYSIS METHOD

2.5 OXIDATION METHOD

2.6 HYDROLYSIS METHOD

2.6.1 Hydrolysis catalyst

2.6.2 Kinetics of catalytic hydrolysis of carbonyl sulfide

2.6.3 Study on the mechanism of catalytic hydrolysis of carbonyl sulfide

2.6.4 Deactivation and regeneration of hydrolysis catalyst

REFERENCES

CHAPTER 3: HYDROLYSIS OF CARBONYL SULFIDE ON AL2O3 BASED CATALYST

3.1 APPLICATION AND RESEARCH OF AL BASED HYDROLYSIS CATALYST

3.2 DEVELOPMENT OF NEW HYDROLYSIS CATALYSTS

3.2.1 gamma-ALO2

3.2.2 Class hydrotalcite

3.3.2 Transition Metals

3.3.3 Other Metals

3.4 INFLUENCE OF TEMPERATURE AND ATMOSPHERE EFFECT ON HYDROLYSIS CATALYST

3.4.1 Temperature

3.4.2 Atmosphere effect

3.5. HYDROLYSIS KINETICS AND MECHANISM

3.5.1 Hydrolysis reaction kinetics

3.5.2 Hydrolysis reaction mechanism

3.6 EFFECT OF TEMPERATURE

3.6.1 hydrolysis performance

3.6.2 XRD analysis

3.6.3 Texture analysis

3.6.4 XPS

3.6.5 CO2-TPD

3.7 EFFECT OF HCL

3.7.1 hydrolysis performance

3.7.2 XRD analysis

3.7.3 Texture analysis

3.7.4 XPS

3.7.5 CO2-TPD

3.8 EFFECT OF DUST CONTAINING FE

3.8.1 hydrolysis performance

3.8.2 XRD analysis

3.8.3 Texture analysis

3.8.4 XPS

3.8.5 CO2-TPD

CHAPTER 4: HYDROLYSIS OF CARBONYL SULFIDE ON ACTIVATED CARBON BASED CATALYST

4.1 SCREENING AND ACTIVITY EVALUATION OF COAL-BASED ACTIVATED CARBON CATALYSTS

4.1.1 Evaluation of the catalytic activity of hydrolyzing COS with Al2O3 supported by coal-based activated carbon

4.1.2 Evaluation of hydrolyzing COS activity on coal-based activated carbon-supported by manganese peroxides

4.1.3 Evaluation of the hydrolyzing activity of CoS-loaded transition metal oxides on coal-based activated carbon

4.1.4 Effect of the Addition of Rare Earth Elements on Catalytic Hydrolyzed COS Activity

4.1.5 Experimental study of catalyst regeneration

4.2 SCREENING AND ACTIVITY EVALUATION OF CATALYSTS USING COCONUT SHELL ACTIVATED CARBON AS THE CARRIER

4.2.1 Preparation of catalyst

4.2.2 Evaluation of Catalyst Activity

4.2.3 Influence of experimental conditions

4.2.4 Experimental research on catalyst regeneration

4.3 KINETIC STUDY OF COS HYDROLYSIS REACTION

4.3.1 COS hydrolysis reaction kinetics preparation experiment

4.3.2 Kinetic experiment of COS hydrolysis reaction

4.4 SUGGESTION OF COS REMOVAL REACTION MECHANISM

REFERENCES

CHAPTER 5: HYDROLYSIS OF CARBONYL SULFIDE ON HYDROTALCITE BASED CATALYST

5.1 PREPARATION AND EVALUATION OF ZNAL AND NIAL HYDROTALCITE DERIVED OXIDE CATALYSTS

5.1.1 ZnAl hydrotalcite-derived oxides catalyze the hydrolysis of carbonyl sulfide

5.1.2 NiAl hydrotalcite-derived oxides catalyze the hydrolysis of carbonyl sulfide

5.2 PREPARATION AND EVALUATION OF ZNNIAL HYDROTALCITE DERIVED OXIDE CATALYSTS

5.2.1 Preparation and evaluation method of ZnNiAl hydrotalcite derived catalysts

5.2.2 Activity evaluation of ZnNiAl hydrotalcite derived catalysts

5.2.3 Effect of the addition of rare earth element cerium on catalyst activity

5.3 SCREENING AND ACTIVITY EVALUATION OF CONIAL HYDROTALCITE-DERIVED COMPOSITE OXIDE CATALYSTS

5.3.1 Evaluation of catalytic COS hydrolysis activity of CoNiAl hydrotalcite-derived composite oxides

5.3.2 Effect of the addition of Rare Earth Elements on Catalytic Hydrolyzed COS activity

5.3.3 Influence of experimental conditions

5.4 DEACTIVATION AND REGENERATION OF HYDROTALCITE-DERIVED OXIDE CATALYSTS

5.4.1 Deactivation of catalyst of hydrotalcite-derived oxide catalyst

5.4.2 Regeneration of catalysts for class hydrotalcite-derived oxide catalysts

5.5 STUDY ON KINETICS AND MECHANISM OF HYDROTALCITE-DERIVED OXIDES CATALYZED COS HYDROLYSIS

5.5.1 Intrinsic kinetics of carbonyl sulfide hydrolysis reaction

5.5.2 Study on hydrolysis mechanism of carbonyl sulfide

REFERENCES

CHAPTER 6: MECHANISM OF HYDROLYSIS OF CARBONYL SULFIDE

6.1 DENSITY FUNCTIONAL STUDY OF CONVERSION OF CARBONYL SULFIDE ON NIO

6.1.1 Model establishment and calculation method

6.1.2 Adsorption and transformation of COS on clean NiO (100) surface

6.1.3 Adsorption and transformation of COS on hydroxylated NiO (100) surface

6.2 THEORETICAL STUDY ON THE REGULATION OF ELECTRONIC STRUCTURE OF NIO BY METAL DOPING AND LOADING

6.2.1 Establishment and calculation method of the model

6.2.2 The regulatory effect of bulk doping on the electronic structure of NiO

6.2.3 Analysis of electron band structure after bulk phase doping

6.2.4 Analysis of state density after bulk phase doping

6.2.5 Charge density analysis after bulk phase doping

6.2.6 The regulatory effect of surface load on the electronic structure of NiO

6.3 SPONTANEOUS FORMATION OF ASYMMETRIC OXYGEN VACANCIES IN TRANSITION METAL DOPED CEO2 NANORODS WITH IMPROVED ACTIVITY FOR COS CATALYTIC HYDROLYSIS

6.3.1 Characterization of CeO2 and MCeO2

6.3.2 Catalytic Performance of CeO2 and MCeO2 for Hydrolysis of COS

6.3.3 DFT Calculations for Catalytic Hydrolysis of COS over CeO2 and MCeO2

REFERENCE