凝聚态物理中的完整量子效应 Full Quantum Effects in Condensed Matter Physics

基本信息

Publisher ‏ : ‎ Cambridge University Press

Publication date ‏ : ‎ January 31, 2026

Language ‏ : ‎ English

Print length ‏ : ‎ 650 pages

ISBN-10 ‏ : ‎ 1009563912

ISBN-13 ‏ : ‎ 978-1009563918

Item Weight ‏ : ‎ 1.74 pounds

信息仅供参考，具体请以实物为准。

书籍简介

随着物理科学的进步，理论模拟越来越能反映真实系统，实验观测也变得更加精确和精细。因此，超越玻恩-奥本海默近似势在必行。本书以薛定谔方程为基础，探讨凝聚态物理，同时考虑了核自由度和电子自由度。本书重点关注两类现象：一类是玻恩-奥本海默近似原则上适用，但在实践中逐渐失效的现象，例如核量子效应；另一类是完全无法应用玻恩-奥本海默近似的现象，例如非绝热效应。在实际系统中，正如本书所强调的，凝聚态物质的完整量子特性在进行精确的模拟或材料性质测量时不容忽视。本书提供了最先进的量子理论和实验方法，对物理、化学、材料科学、能源和环境科学等领域的本科生、研究生、研究人员和行业专业人士都极具价值。

• 阐述了核量子效应和非绝热效应如何对凝聚态计算物理中某些物理性质的描述产生不利影响，而迄今为止，计算物理往往忽略了这些影响。

• 描述了理论和实验研究方法。

• 建议将所包含的研究方法应用于其他领域，例如能源和环境科学。

As physical science advances, theoretical simulations become increasingly reflective of realistic systems, and experimental observations become more precise and refined. Thus, going beyond the Born–Oppenheimer approximation is inevitable. This book bases its discussion of condensed matter physics on the Schrödinger equation, considering both nuclear and electronic degrees of freedom. Particular attention is given to two types of phenomena: those, such as nuclear quantum effects, for which the Born–Oppenheimer approximation, although applicable in principle, is progressively weakened in practice, and those that cannot be applied at all, such as phenomena exhibiting non-adiabatic effects. In practical systems, the full quantum nature of condensed matter, as emphasized in this book, cannot be overlooked when performing accurate simulations or measurements of material properties. This book offers state-of-the-art quantum theoretical and experimental methods, valuable for undergraduates, graduates, researchers, and industry professionals in fields such as physics, chemistry, materials science, energy, and environmental science.

Demonstrates how nuclear quantum effects and non-adiabatic effects can have detrimental consequences for the description of certain physical properties in the context of condensed-matter computational physics, which has so far often ignored these consequences

Describes both theoretical and experimental research methods

Suggests the application of the included research methods to other fields, such as energy and environmental science

章节内容

前言；1. 凝聚态物质中全量子效应概述；2. 凝聚态物理中的全量子效应；3. 化学中的全量子效应；4. 基本理论：电子结构；5. 全量子效应理论；6. 全量子效应实验；7. 典型的全量子效应体系：氢；8. 典型的全量子效应体系：其他元素；9. 全量子效应在能源应用中的应用；10. 全量子效应在环境应用中的应用；11. 全量子效应在器件应用中的应用；附录A；附录B；参考文献；索引。

Preface; 1. Overview of full quantum effects in condensed matter; 2. Full quantum effects in condensed matter physics; 3. Full quantum effects in chemistry; 4. Basic theory: electronic structure; 5. Theory for full quantum effects; 6. Experiments for full quantum effects; 7. Typical full-quantum-effect system: hydrogen; 8. Typical full-quantum-effect systems: other elements; 9. Full quantum effects in energy applications; 10. Full quantum effects in environmental applications; 11. Full Quantum effects in device applications; Appendix A; Appendix B; References; Index.

图书评论

评论 1

“本书填补了凝聚态物理领域的一个关键空白，探讨了超越玻恩-奥本海默近似的必然趋势——随着模拟精度日益接近实验精度和实际精度，本书的出版可谓恰逢其时。本书以薛定谔方程为基础，严谨地探讨了电子-核耦合动力学，重点关注一些被忽视的现象：玻恩-奥本海默近似在核量子效应中的适用性降低，以及在非绝热情况下的完全失效。本书融合了前沿量子理论和实验成果，可为物理学、材料科学、能源科学等领域的本科生、研究生、研究人员和行业专业人士提供指导，帮助他们进行精确的材料性质研究和跨学科应用。这是一部对该领域具有里程碑意义且影响深远的著作。” ——张富春院士，中国科学院大学

评论 2

“本书对凝聚态物理中的核量子效应和非绝热效应进行了简洁而权威的介绍，是学生和研究人员的理想之选。本书及时而全面地介绍了凝聚态系统中的完整量子效应，为研究生和研究人员提供了理解超越玻恩-奥本海默近似的核量子效应和非绝热效应的宝贵资源。”——安吉尔·鲁比奥，马克斯·普朗克物质结构与动力学研究所，弗莱特隆研究所计算催化计划

评论 3

“本书探讨了凝聚态物质中量子效应这一有趣而重要的问题。它解释了理解这些效应的基本原理和方法，并通过物理、材料、化学等领域中大量引人入胜的量子效应实例，生动地展现了这些效应的重要性。”这本应用宝库也展现了该领域最前沿的实验、理论和模拟之间近乎共生的关系。我相信不同阶段的读者都能从本书中受益。——安杰洛斯·迈克尔德斯，剑桥大学

Review 1

'This book fills a critical gap in condensed matter physics by addressing the inevitable shift beyond the Born–Oppenheimer approximation – a timely endeavor as simulations increasingly approach experimental and realistic precision. Grounded in the Schrödinger equation, it rigorously explores electron–nuclear coupling dynamics, focusing on overlooked phenomena: The diminished applicability of the Born–Oppenheimer approximation in nuclear quantum effects and its complete inapplicability in nonadiabatic scenarios. Integrating cutting-edge quantum theories and experimental findings, the book can serve undergraduates, graduates, researchers, and industry pros across physics, materials science, energy science, and more – guiding accurate material property studies and cross-disciplinary applications. A pivotal, far-reaching work for the field.'  -——张富春院士, University of Chinese Academy of Sciences

Review 2

'A concise and authoritative introduction to nuclear quantum and nonadiabatic effects in condensed matter physics, ideal for students and researchers alike. This book provides a timely and comprehensive introduction to full quantum effects in condensed matter systems, offering graduate students and researchers an invaluable resource to understand nuclear quantum and nonadiabatic effects that go beyond the Born–Oppenheimer approximation.' Angel Rubio, Max Planck Institute for the Structure and Dynamics of Matter, and Initiative for Computational Catalysis at the Flatiron Institute

Review 3

'This book tackles the interesting and important question of quantum effects in condensed matter. It explains the underlying principles and approaches used to understand these effects. Then it brings the importance of these effects to life through numerous fascinating demonstrations of quantum effects in physics, materials, chemistry, and more. This veritable treasure trove of applications also showcases the almost symbiotic relationship there is in this field between state-of-the-arts experiment, theory, and simulation. I can see readers at various stages of advancement benefitting from this book.' Angelos Michaelides, University of Cambridge

作者简介

王恩戈是北京大学荣誉校长、卡弗里理论科学研究所名誉所长、物理学讲席教授。他因对轻元素材料全量子效应的研究而闻名。王恩戈是中国科学院院士、美国物理学会会士，曾荣获多项奖项，包括陈嘉庚数学与物理学科学奖、洪堡研究奖和发展中国家科学院物理学奖。他已发表论文350余篇，担任过10余种国际期刊的编辑或编委，并合著了两部专著：《分子与凝聚态物质的计算机模拟：从电子结构到分子动力学》（世界科学出版社，2018年）和《水：基础科学》（施普林格出版社，2023年）。

Enge Wang is President Emeritus of Peking University, Honorary Director of Kavli Institute of Theoretical Sciences, and a Chair Professor of Physics. He is renowned for his research on full quantum effects in light-element materials. A member of the Chinese Academy of Sciences and a Fellow of the American Physical Society, Wang has been honoured with a series of awards, including the Tan Kah Kee Science Award in Mathematics and Physics, the Humboldt Research Award, and the TWAS Award in Physics. He has co-authored over 350 papers, edited and been a member of editorial boards of over 10 international journals, and co-authored two books: Computer Simulations of Molecules and Condensed Matter: From Electronic Structures to Molecular Dynamics (World Scientific, 2018), and Water: Basic Science (Springer, 2023).